Kinetics and Mechanism of Complex Formation of Nickel(II) with 1-(2-Pyridylazo)-2-naphthol in Acetic Acid
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چکیده
منابع مشابه
Determination of ultra trace amount Chromium in water samples with the 1-(2-PyridylAzo)-2-Naphthol, (PAN) by the bromate ion in sulfuric acid with kinetic spectrophotometric method
A new kinetic spectrophotometic method for the determination of trace amount Chromium (III) in Teareal samples has been described based on it s the catalytic effect on the oxidations of 1 - ( 2 –PyridylAzo ) - 2 - Naphthol, (PAN), by potassium bromated in sulfuric acid. The reaction is followedspec- trophotometrically by measuring the decrease in the absorbance at 469 nm. Under the optimumcondi...
متن کاملLiquid chromatography of palladium and non-ferrous metal chelates with 1-(2-pyridylazo)-2-naphthol.
1-(2-Pyridylazo)-2-naphthol has been used for extraction concentration of palladium, copper, cobalt and nickel from aqueous solutions and subsequent separation of the chelates obtained, by means of high-pressure liquid chromatography. A technique for determining microamounts of palladium in aqueous solutions in the presence of 100-fold ratio of copper and 80-fold ratio of cobalt has been develo...
متن کاملdetermination of ultra trace amount chromium in water samples with the 1-(2-pyridylazo)-2-naphthol, (pan) by the bromate ion in sulfuric acid with kinetic spectrophotometric method
a new kinetic spectrophotometic method for the determination of trace amount chromium (iii) in teareal samples has been described based on it s the catalytic effect on the oxidations of 1 - ( 2 –pyridylazo ) - 2 - naphthol, (pan), by potassium bromated in sulfuric acid. the reaction is followedspec- trophotometrically by measuring the decrease in the absorbance at 469 nm. under the optimumcondi...
متن کاملPolymer-Controlled Synthesis of 1-(2-Pyridylazo)-2-Naphthol Hierarchical Architectures
The self-assembly of organic 1-(2-pyridylazo)-2-naphthol (PAN) into hierarchical architectures, such as microfibers, microrods, and sheaflike structures, in solution was successfully achieved by reprecipitation method with the assistance of thermoresponsive diblock copolymer poly(N,N-dimethylacrylamide)-b-poly(N-isopropylacrylamide) (PDMA-b-PNIPAM). It was found that the morphology modification...
متن کاملCloud Point Extraction of Palladium as Chelate with 1-(2-pyridylazo)-2-naphthol Using Triton X-114 Prior to Determination in Real Samples by ETAAS
A pre-concentration and determination methodology for palladium in real samples at ultra-trace levels by 1-(2-pyridylazo)-2-naphthol (PAN) was developed. The analyte in the initial aqueous solution, acidified with HCl, was complexed with PAN and Triton X-114 was added as a surfactant. The surfactant-rich phase was diluted with concentrated HNO3 (65%, w/w) after phase separation. Then, the conce...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1984
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.57.1255